
A rendering of protons, neutrons and electrons in an atom.
Virginia Commonwealth University researchers have achieved a feat
that is a first in the fields of physics and chemistry — one that could
have wide-ranging applications.
A team in the lab of Puru Jena, Ph.D., a distinguished professor in the
Department of Physics in the
College of Humanities and Sciences,
has created the most stable tri-anion particle currently known to
science. A tri-anion particle is a combination of atoms that contains
three more electrons than protons. This discovery is novel because
previously known tri-anion particles were unstable due to their
numerical imbalance. These unstable particles dispel additional
electrons, interrupting chemical reactions.
Jena partnered with Tianshan Zhao, a graduate student in the physics
department; Jian Zhou, Ph.D., a postdoctoral fellow; and Qian Wang,
Ph.D., a physics professor at Peking University, to use quantum
mechanical calculations to create computer models to prove the stability
of the BeB11(CN)12 tri-anion. This tri-anion is made of the elements boron and beryllium and the chemical compound cyanogen.
The researchers’ work will be featured on the cover of Angewandte Chemie, a world-renowned chemistry journal, on
Oct. 17. The
team’s article was
designated a VIP paper by the publication, which means it is considered
among the top five percent of papers for its contribution to the study
of chemistry.
“This is very important in this field, nobody has ever found such a
tri-anion,” Jena said. “Not only can it keep three electrons but the
third electron is extremely stable. The guiding principles we have used
in this paper will help with the design of other tri-anions. The
question is: What do we do with this knowledge?”
Puru Jena, Ph.D.
Real world applications
The tri-anion may have a number of industrial
applications. So far, Jena and his team have hypothesized that the
particle may be used in the creation of an aluminum ion battery, which
has distinct advantages over the widely used rechargeable lithium ion
battery. Aluminum is in greater supply than lithium and is less
reactive.
During the chemical reaction that would power the battery, the
tri-anion would make the battery conductive by moving from one of its
electrodes to the other.
While a battery is the only demonstrated use so far, existing
applications for other particles with one additional electron, called
mono-anions, and two additional electrons, called di-anions, show the
potential of Jena’s work.
“Such particles are very important for many reasons. Number one, they
make salts. Secondly, they are used in all kinds of chemical compounds,
such as those in floor cleaners as oxidizing agents that kill
bacteria,” Jena said. “They are also used to purify air, which is a
billion-dollar industry, and in mood enhancers, similar to what Prozac
does. The potential uses are endless.”